Organometallic Bonding And Reactivity
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Organometallic Bonding And Reactivity
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Author : J.M. Brown
language : en
Publisher: Springer
Release Date : 2003-07-01
Organometallic Bonding And Reactivity written by J.M. Brown and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2003-07-01 with Science categories.
The making and breaking of carbon-metal bonds is fundamental to all the processes of organometallic chemistry and metal mediated homogeneous or heterogeneous catalysis. The ever expanding scope of highly specific stoichiometric and catalytic transformations or organic substrates involving metals requires a thorough physical and theoretical understanding of fundamental principles of organometallic structure and reactivity. Diffraction experiments form the basis of tailoring the molecular architecture of organometallic compounds for specific functions. Mass spectrometric techniques possess the power to provide direct information on the energetics of transient species generated in the gas-phase. Computational chemistry with ab initio or density functional methods make a reliable numerical assessment of structures and (relative) energies increasingly feasible. Embedding methods, combining quantum chemistry with force field of semiempirical MO treatments, quantum dynamic studies and the computational modelling of solvent effects extend the utility of the basic methods. This volume in the series Topics in Organometallic Chemistry presents a survey by renowned experts of important experimental and theoretical developments to elucidate basic aspects of bonding, energetics, reaction mechanisms, molecular geometries and solid-state structures of organometallic compounds. Written by authors with frontier research expertise in their fields, both experimental and quantum chemical techniques, methodologies, results and interpretations are detailed in a manner suitable for the non-specialist, who seeks state-of-the-art information in the respective field.
Organometallic Bonding And Reactivity
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Author : J.M. Brown
language : en
Publisher: Springer
Release Date : 2014-03-12
Organometallic Bonding And Reactivity written by J.M. Brown and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2014-03-12 with Science categories.
Reactivity And Bonding In Transition Organometallic Compounds
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Author :
language : en
Publisher:
Release Date : 1970
Reactivity And Bonding In Transition Organometallic Compounds written by and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1970 with Chemical bonds categories.
Transition Metal Carbonyl Cluster Chemistry
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Author : Paul J. Dyson
language : en
Publisher: CRC Press
Release Date : 2018-10-03
Transition Metal Carbonyl Cluster Chemistry written by Paul J. Dyson and has been published by CRC Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 2018-10-03 with Science categories.
Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Organometallics
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Author : Manfred Bochmann
language : en
Publisher:
Release Date : 1993
Organometallics written by Manfred Bochmann and has been published by this book supported file pdf, txt, epub, kindle and other format this book has been release on 1993 with Organotransition metal compounds categories.
The interaction of transition metals with unsaturated organic molecules has led to fundamental insights in the nature of the chemical bond which, in turn, have provided the basis of important present-day applications such as transition metal mediated synthesis or homogeneous and heterogeneous catalysis. This slim volume outlines the chemistry and discusses the bonding in some of the most important classes of organometallic compounds: the complexes of transition metals with [pi]-ligands such as alkenes, alkynes, arenes, and cyclopentadienyl and allyl ligands. The material covered follows on from Organometallics 1 which covers the chemistry of complexes with metal-carbon [sigma]-bonds. Synthetic and reactivity aspects of each class of compounds are illustrated with pertinent examples from the recent chemical literature. Highlighted excursions relate the fundamental chemistry to current synthetic or catalytic applications.
Advances In Organometallic Chemistry
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Author :
language : en
Publisher: Academic Press
Release Date : 1996-02-12
Advances In Organometallic Chemistry written by and has been published by Academic Press this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-02-12 with Technology & Engineering categories.
This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964. Almost all branchesof chemistry now interface with organometallic chemistry--the study of compounds containing carbon metal bonds. Organometallic compounds range from species which are so reactive that they only have a transient existence at ambient temperatures to species which are thermally very stable. Organometallics are used extensively in the synthesis of useful compounds on both large and small scales. Industrial processes involving plastics, polymers, electronic materials, and pharmaceuticals all depend on advancements in organometallic chemistry. In basic research, organometallics have contributed inter alia to: Metal cluster chemistry Surface chemistry The stabilization of highly reactive species by metal coordination Chiral synthesis The formulation of multiple bonds between carbon and the other elements and between the elements themselves
Metals And Ligand Reactivity
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Author : Edwin C. Constable
language : en
Publisher: Wiley-VCH
Release Date : 1996-01-18
Metals And Ligand Reactivity written by Edwin C. Constable and has been published by Wiley-VCH this book supported file pdf, txt, epub, kindle and other format this book has been release on 1996-01-18 with Science categories.
Edwin C. Constable Metals and Ligand Reactivity An Introduction to the Organic Chemistry of Metal Complexes New, revised and expanded edition This book is a highly readable introduction to the reactions of coordinated ligands, which have become a useful tool in organic synthesis. Bridging the gap between the traditional fields, this text presents the basic concepts of ligand reactivity as well as synthetic applications of these reactions. Topics covered include Principles of metal-ligand interaction Reactions of coordinated ligands with nucleophiles and electrophiles Oxidation and reduction of coordinated ligands Cyclic and encapsulating ligands, template effects and supramolecular chemistry Carefully selected examples, lucidly designed figures and schemes as well as numerous study problems make this book an ideal guide for students and practitioners of organic synthesis. References to further reading are also included.
Organometallics Complexes With Transition Metal Carbon Pi Bonds
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Author : Manfred Bochmann
language : en
Publisher: Oxford University Press, USA
Release Date : 1994
Organometallics Complexes With Transition Metal Carbon Pi Bonds written by Manfred Bochmann and has been published by Oxford University Press, USA this book supported file pdf, txt, epub, kindle and other format this book has been release on 1994 with Religion categories.
"This series of short texts provides accessible accounts of a range of essential topics in chemistry. Written with the needs of the student in mind, the Oxford Chemistry Primers offer just the right level of detail for undergraduate study, and will be invaluable as a source of material commonly presented in lecture courses yet not adequately covered in existing texts. All the basic principles and facts in a particular area are presented in a clear and straightforward style, to produce concise yet comprehensive accounts of topics covered in both core and specialist courses." "The interaction of transition metals with unsaturated organic molecules has led to fundamental insights in the nature of the chemical bond which, in turn, have provided the basis of important present-day applications such as transition metal mediated synthesis or homogeneous and heterogeneous catalysis. This slim volume outlines the chemistry and discusses the bonding in some of the most important classes of organometallic compounds: the complexes of transition metals with [pi]-ligands such as alkenes, alkynes, arenes, and cyclopentadienyl and allyl ligands. The material covered follows on from Organometallics 1 which covers the chemistry of complexes with metal-carbon [sigma]-bonds. Synthetic and reactivity aspects of each class of compounds are illustrated with pertinent examples from the recent chemical literature. Highlighted excursions relate the fundamental chemistry to current synthetic or catalytic applications."--BOOK JACKET.Title Summary field provided by Blackwell North America, Inc. All Rights Reserved
Polar Organometallic Reagents
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Author : Andrew E. H. Wheatley
language : en
Publisher: John Wiley & Sons
Release Date : 2022-03-03
Polar Organometallic Reagents written by Andrew E. H. Wheatley and has been published by John Wiley & Sons this book supported file pdf, txt, epub, kindle and other format this book has been release on 2022-03-03 with Science categories.
Outlines recent advances in the field of polar organometallic chemistry, particularly in the context of the emergent areas of synergic and cooperative species. Polar Organometallic Reagents provides a critical overview of developments in the field of modern polar organometallic chemistry. With a particular focus on the emergent area of synergic heterometallic reagents, this timely volume describes our attempts to understand recently developed polar organometallics and their application in a range of new directions. Contributions from leading researchers present new synthetic work and discuss recent advances in characterization techniques, synthetic applications, and mechanistic understanding of heterometallic complexes. In-depth chapters provide detailed information on fundamental, structural, and theoretical aspects of polar organometallic chemistry while articulating the need and rationale for the advent of new reagents. Topics include alkali and alkaline earth organometallics, synergy and cooperativity, cationic p-block clusters and other developments in main group catalysis, synthetic trends in alkenyl copper, ate complex and borylmetal chemistry, non-traditional reaction environments, and trends in developing greener processes. Designed to keep readers updated with the latest progress in the field, this much-needed book: Includes an introductory chapter outlining the development of synergic bases and the logic behind their creation Highlights the role of solid-state structural work in elucidating the bonding and reactivity displayed by modern polar organometallics Examines the use of calculations in catalyst design and plotting more sustainable reaction pathways Discusses modern trends in solution techniques that have achieved new insights into the structures of active species Presents striking advances in the ease of handling of polar organometallics and the emergence of main group catalysis Polar Organometallic Reagents is essential reading for researchers in chemical disciplines including synthetic inorganic and coordination chemistry, main group chemistry, organometallic chemistry, organic synthesis and catalysis.
C H Bond Activation And Catalytic Functionalization Ii
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Author : Pierre H. Dixneuf
language : en
Publisher: Springer
Release Date : 2016-03-10
C H Bond Activation And Catalytic Functionalization Ii written by Pierre H. Dixneuf and has been published by Springer this book supported file pdf, txt, epub, kindle and other format this book has been release on 2016-03-10 with Science categories.
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.